@article{doi:10.1063/1.3663632,
title = {Optical near-field induced visible response photoelectrochemical water splitting on nanorod TiO2},
author = {Thu Hac Huong Le and Kazuma Mawatari and Yuriy Pihosh and Tadashi Kawazoe and Takashi Yatsui and Motoichi Ohtsu and Masahiro Tosa and Takehiko Kitamori},
url = {https://doi.org/10.1063/1.3663632},
doi = {10.1063/1.3663632},
year = {2011},
date = {2011-11-01},
urldate = {2011-11-01},
journal = {Applied Physics Letters},
volume = {99},
number = {21},
pages = {213105},
abstract = {Here we report a way to induce the visible response of non-doped TiO2 in the photocatalytic electrochemical water splitting, which is achieved by utilizing the optical near-field (ONF) generated on nanorod TiO2. The visible response is attributed to the ONF-induced phonon-assisted excitation process, in which TiO2 is excited by sub-bandgap photons via phonon energy. Our approach directly gets involved in the excitation process without chemical modification of materials; accordingly it is expected to have few drawbacks on the photocatalytic performance. This study may offer another perspective on the development of solar harvesting materials.},
keywords = {nanorod, Near-field effect, TiO2, Water splitting},
pubstate = {published},
tppubtype = {article}
}